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Will faces unforeseen challenges on his first day at his new job. Katie receives her first assignment. Maddie reconnects with an old acquaintance. Carlos pays the price for Will’s collaboration.

Three months have passed since the tragedy at Mount Weather and our heroes learn that a bounty has been put on Clarke’s head. Unbeknownst to Clarke, a team led by Bellamy and Kane journeys deep into Grounder territory to save her. Meanwhile, Murphy finds his way to the mansion and discovers a very different Jaha on a very different mission.

As the clock counts down to the end of the world, Tommy finds himself up against his biggest challenge yet as Erica takes drastic measures to see her plan succeed. Malina tries to fulfill her great-grandmother’s prophecy to save the world with the help of Luke and Quentin. Emily and Ren desperately search for Miko. Carlos is faced with a life and death choice.

In the year 2166, the immortal villain Vandal Savage is on the verge of his final victory – total chaos and the utter destruction of humanity. As the world crumbles, the Time Master Rip Hunter takes matters into his own hands; he travels 150 years into the past to assemble a carefully selected team of heroes and rogues to stop him. Hunter has chosen what seems like an ill-matched group: billionaire inventor Ray Palmer, who has created an exo-suit with the power to shrink him to miniscule size, as the Atom; Sara Lance, the White Canary, a trained assassin; Professor Martin Stein and Jefferson “Jax” Jackson, who together form the meta-human Firestorm; Leonard Snart, known as Captain Cold, and his partner Mick Rory, AKA Heat Wave, a pair of career criminals; and Kendra Saunders and Carter Hall AKA Hawkgirl and Hawkman. Together this unlikely group will attempt to stop one of the most formidable villains of all time, while they must learn how to not only be a team, but heroes as well.

Oliver must deal with the devastating consequences of Darhk’s last attack. Seeking revenge, Oliver goes on a brutal manhunt looking for Dahrk.

Brian embarks on his first FBI field assignment when he travels to Quantico to lend his skills to the bureau unit that catches serial killers. However, the trip takes a negative turn when Brian realizes the man he’s working with may have put away an innocent person in the career-making case that made him a renowned profiler. Also, Brian tries to stay one step ahead of Rebecca as she comes closer to discovering Senator Morra’s connection to NZT.

Peggy moves to the City of Angels to help Chief Daniel Sousa at the West Coast Strategic Scientific Reserve (SSR) investigate a bizarre homicide involving an alleged killer and Isodyne Energy, and reunites with some familiar faces.

Peggy discovers her murder investigation has huge ramifications that can destroy her career, as well as everyone near and dear to her.

With the knowledge that Valentine is alive and on the hunt for The Mortal Cup, the Institute is on high alert. Not wasting any time, Jace jumps into action and figures Clary’s memories are the key to finding Jocelyn and The Mortal Cup. Unfortunately, Clary’s memories were wiped leaving her without any recollection of this other life that could help her and the team. With only one other option remaining, Jace, Isabelle and a very reluctant Alec take Clary to the City of Bones to face the powerful Silent Brothers. Meanwhile, Luke continues his search for Clary, and Simon tries to come to terms with his best friend’s new life.

Now that they’ve grown closer, Barry considers telling Patty that he is The Flash. Meanwhile, Joe and Iris try to get to know Wally, and the team hunts down a meta-human who can slow time itself.